新型锁磷剂组合混凝剂调控富营养化水体沉积物研究

    Study on the inhibition of eutrophic water sediment by new phosplock and coagulants

    • 摘要: 沉积物中磷的释放和藻类复苏是导致藻类水华频繁发生的主要原因之一。本研究以福建省富营养化山仔水库沉积物为研究对象,通过实验室模拟实验探究新型锁磷剂对沉积物磷释放控制和藻类复苏的抑制效果。实验结果表明,投加新型锁磷剂使得沉积物总磷(TP)和较稳定的钙结合态磷(Ca-P)分别增加10.8%和15.9%,减少了沉积物中磷的释放。实验过程中,以水体和表层沉积物中磷酸含量投加理论计量100∶1的新型锁磷剂藻类复苏的抑制率仅有34.0%;投加两倍计量的锁磷剂显著提高了对沉积物藻类萌发的抑制能力,达到了69.2%,但同时重金属残留引起的生态风险增大且成本较高;推荐用量锁磷剂组合了60 mg/L的聚合氯化铝(PAC)或硅藻土,具有较好的抑藻率且改变了水体中浮游植物的群落结构组成。因此,修复富营养化水体时,需要综合评估抑藻率、药剂成本和生态风险,因地制宜地将新型锁磷剂与混合剂组合联用可以达到更好的调控效果。

       

      Abstract: One of the primary reasons for frequent algal blooms are the release of phosphorus and the algae recovery in sediments.Therefore,the deposits of the eutrophic Shanzi Reservoir in Fujian Province were taken as the research object and laboratory simulation experiments were carried out to explore the inhibitory effect of new phosphorus-locking agent(NP)on the release of phosphorus in the sediments and the recovery of algae.The experimental results showed that the addition of NP increased the total phosphorus(TP)and the calcium-bound phosphorus(Ca-P)of the deposit by 10.8% and 15.9%,respectively.The theoretical amount(NP:P=100:1)of the NP's inhibition rate only reached 34.0% during the experiment.Adding twice as much NP improved phytoplankton germination inhibition in sediments by 69.2%,but the cost was higher and the ecological risk of heavy metal residues had increased,the method of combining 60 mg/L Polyaluminum Chloride(PAC)or Diatomaceous earth(DIA)with the theoretical amount of NP also had a better effect and changed the structure of the phytoplankton community in water.Therefore,the algae inhibition rate,the cost,and ecological risks should be comprehensively considered and choosing a suitable combination of NP and coagulants could have a better effect to treat eutrophic water.

       

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